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For electrons in atoms we make a clear distinction between electron spin and electron orbital angular momentum, and then combine them to give the total angular momentum.

Spin angular momentum of nucleus. In quantum mechanics and particle physics, spin is an intrinsic form of angular momentum carried by elementary particles, composite particles (), and atomic nuclei. It is common practice to represent the total angular momentum of a nucleus by the symbol I and to call it "nuclear spin". Spin is one of two types of angular momentum in quantum mechanics, the other being orbital angular momentum.The orbital angular momentum operator is the quantum-mechanical counterpart to the classical angular momentum of orbital.

Small changes in the spatial alignment of these orbits lead to changes in the angular momentum (or spin) of the nucleus. There are two quantum numbers associated with the spin angular momentum momentum that determine its properties. Spin angular momentum is a specific type of angular momentum possessed by some nuclei.

H Zeeman = − 1 2 π ∑ i γ i (1 − σ ZZi) B 0 I Zi where γi is the magnetogyric ratio of the i th nucleus, and IZi is the component along Z of the nuclear spin angular momentum operator, Ii. The contribution, H Zeeman, to the nuclear spin Hamiltonian, in units of hertz, has the form:. The spin angular momentum S of the nucleus and the neutron, and their orbital angular momentum vector L, are expressed in units of the reduced Planck’s constant ℏ = h / 2π.

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